Please contact Yale Environmental Health and Safety for latest Regulatory Requirements. Manufactured, Dispelling the Myths of Heat Transfer Fluids Kevin Connor The Dow Chemical Company Heat Transfer Chill Water Loop Secondary Coolant (Heat Transfer Fluid) Primary Refrigerant Expansion Device Air Handler, Eastman plasticizers Bulk storage guidelines This publication contains general information on the bulk storage of Eastman plasticizers, including guidelines for tank components and materials, as well as, TECHNIQUES FOR NATURAL GAS SAMPLING A DISCUSSION OF FIELD METHODS FOR OBTAINING SPOT SAMPLES Randall Messman SW Regional Sales Manager PGI International 16101 Vallen Drive Houston, TX 77041 Purpose Natural. 2. The Styrene Monomer Safe Handling Guide 2018 update has been published, as a result of several months collaborative work with the main styrene manufacturers and under the coordination of PlasticsEurope (the association that represents plastics manufacturers active in the European plastics industry, including styrene manufacturers and its derivatives). Styrene i s readily polymeri zed and copolymerized by both batch and continuous processes (mass, emulsion, suspension and solution polymerization). The availability of written styrene usage, health hazard and tra ining program procedures. Small trial blend s should be made to determine the feasibility of this approach. SECTION 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: Collapsible Bulk Containers, Ontario Fire Code SECTION 5.13 DIP TANKS. Pumps should not be subjected to fo rces beyond specified pump tolerances. It should be noted that sufficient oxygen must be present for inhibition. PRODUCT & COMPANY IDENTIFICATION Prepared on: Month, Year Manufactured, Monument Chemical bvba Johann Haltermann Ltd. Haven 1972, Ketenislaan 3 16717 Jacintoport Blvd. Manual Sheet TC-4, Chemical Manufacturer s Association Recommended Practice for Unloading Flammable Liquids from Tank Cars NFPA 30 - Flammable and Combustible Liquids Code NFPA 70 - National Electrical Code NFPA 77 - Recommended Practice on Static Electricity API RP 2003 Protection Against Ignitions Ari sing Out of Static, Lightning, and Stray Currents 6. T he training program should include the following: 1. To facilitate mixing where external refrigeration is employed, it is recommended that eith er the outlet line o r the inlet lin e operate through a floating swing-pipe, adjusted so that the monomer is always eit her withdrawn or discharged a few inch es below the surface. STATIC ELECTRICITY AND GROUNDING Static electricity can cause difficulties such as fires and explosions unless certain precautions are observed. 24 JULY 2011 (PRINT). Caution should be use d, however, sin ce color does not always blend proportionately. Styrene_HSE_brochure_EN_20181211.pdf (550.93 KB) July 2018. 0. Oxy-Fuel Gas Welding. Market data; Position papers; Publications; Videos; Eco-profiles; Education; CP Pallets registration; Stay updated. D2121 Polymer Content of Styrene Monomer 4. This includes, in addition to t he tank, all internal surfaces of nozzles, manholes, manhole covers, internal fittings and all surfaces that may contact the liquid con tents of the tank o r be exposed to vapors fro m the liquid. Consider selecting nonmetallic (PEEK) wear ri ngs to mini mize damage if the pumps run dry. We will manage pro duct stewardship issues by providing customers, distributors and traders with information regarding potential hazards and appropriate safe use and handling of our products. Bulk storage guidelines. 14 JULY 2011 (PRINT), 20 A TBC concentrate for use in increasing the inhibitor level in styren e monomer can be prepared by dissolving 704 grams of pure TBC in 1 gal of styrene monomer (186 gram/liter). Chemical Product Identification Generic Name: Microcrystalline Wax INCI Name: Microcrystalline Wax Chemical Family: Mineral Emergency Telephone Numbers: Page 1, Safety Data Sheet Issue Date: 04-Oct-2013 Version Number: 1 Product Identifiers Product Name: Bright Dyes FLT Yellow/Green Liquid Product Number: 106001 Recommended Use & Restrictions on Use Water tracing. PREVENTION OF POLYMERIZATION Polymerization during storage may be prevented by close atte ntion to monome r temperature, inhibitor level, polymer conte nt and oxygen content. Introduction II. 2. The time req uired for TBC concentrations to fall to a dan gerously low level varie s greatly because of different storage and handling conditions. Use an approved pump to unload the tank car. First developed in 1928, styr ene is today one of the mo st important monomers produced by the chemical industry. Product Name: Phone: Items: Formula Code: A discussion of condensate removal systems for clarifier and thickener drives for water and wastewater facilities. SDS Date: 2/24/15 Crawling Insect Killer 2 EPA Reg.. 9688-111-8845 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION CAS #: Product Use: Manufacturer: Aerosol Flying and Crawling Insect Killer Aerosol Chemsico, A discussion of condensate removal systems for clarifier and thickener drives for water and wastewater facilities. Product Safety Summary Sheet DuPont Vinyl Acetate Chemical Identification, Product Identification or Common Name: CAS number: 108-05-4 CAS name: Acetic acid ethenyl ester EC Number: 203-545-4 IUPAC name: Overview Compressed gas cylinders are used in many workplaces to store gases that vary from extremely flammable (acetylene) to extremely inert (helium). PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : Use of the : Hard Surface Cleaner Substance/Mixture Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1, OIL CONDITION MONITORING: AUTOMOTIVE ANALYSIS Why Analyse Lubricants? Corporate Compliance Team 1666 East Touhy Avenue, CONTAMINANT REMOVAL FROM CENTRIFUGAL SYSTEMS. Kevin Connor The Dow Chemical Company, Eastman plasticizers. If an inert gas blanket such as nitrogen is used, provisions should be made to aerate the monomer once a week for app roximately 30 minutes, or until the oxygen level again reaches saturation. (To comply with OSHA s Hazard Communication Standard 29CFR 1910.1200/ANSI z400. Polymerization becomes self-sustaining above 95°C [MCA SD-37, 1971]. Description Air Eliminators and Combination Air Eliminator Strainers are designed to provide separation, elimination and prevention of air in piping systems for a variety of installations and conditions. Operators wearing rubber-soled shoes, particularly on certain composition floors made of good insulating materials, may pick up considerable static electricity. Additional accidental release, fire an d health information is presented in a su bsequent section of this brochure. 7021, Viton, Teflon, Durable Nitrile, Grafoil GHE, o r its eq uivalent is satisfactory for flanged connections at ambient conditions. 4. Piping. : 100 -42-5 REACH registration No. JULY 2011 (PRINT) 11, 17 When loading or unloading tank cars: 1. FILTERS Since small amounts of f oreign matter may enter storage tanks from various sources, a filter in the t ransfer piping between t he tank and processing equipment is re commended. Product and company identification Trade name of product Product use Product dilution information : OASIS 259 GLASS FORCE : Glass Cleaner : Up to 12.5, CONTAMINANT REMOVAL FROM CENTRIFUGAL SYSTEMS BULLETIN 240-10-3 June 2004 Supersedes June 1983 Many centrifugal systems get little maintenance. 19, Interscience, New York, 1968, p J. Petro and C. P. Smyth, J. Amer. Chem. Successful implementation of this management syste m will ens ure health, safety, and environmental protection are an integral part of designing, manufacturing, marketing, distributing, using, recycling and disposing of our products. For large r piping, butt welded fittings are preferred. STAYFLEX CORROSION CONTROL AND THERMAL INSULATION SYSTEM Installed in Pre-engineered Steel Buildings Provides Lowest Cost Construction Method for CORROSIVE AND WET Environments PREFERRED SOLUTIONS, INC. 2 Environmental, Health & Safety Policy Americas Styrenics is committed to safety excellence. 2. Soc., 80, 73 (1958). ( C) PPM JULY 2011 (PRINT), 10 Property Value Solubility: Styrene in water 8 Temp. Lower the bottle to near the bottom of the tank an d pull out the stopp er with a sharp jerk of the chain. Most consuming locations insulate storage tanks to dampen the effect of high daytime temperatures but do n ot install refrigeration due to cost. ), Styrene: Its Polymers, Copolymers, and Derivatives, Reinhold, New York, 1952, Ch W. H. Lane, Ind. Product identifier Product form : Substance Trade name : STYRENE INHIBITED MONOMER Chemical name : Vinyl benzene, styrene monomer, phenylethylene, ethenyl … If this evolved heat ca nnot be dissipated rapidly enough, the temperature of the monomer will rise, increasing the rate of polymerization and, wit h it, the rate of evolution of heat. Heresite P403 Heresite Chemical Co. 822 South 14th Street Manitowac, WI Lithcote Phenolic Lithcote Corporation LC West Jackson Blvd. Expert Tutors Contributing. Chemical Product and Company Identification Trade Name of this Product Manufacturer Contact Name Lawson Products, Inc. Corporate Compliance Team 1666 East Touhy Avenue, Material Safety Data Sheet OASIS 259 GLASS FORCE 1. Preceding are discussed in detail in the dark at normal ambient temperatures but rapidly! Surface is recommended for marine vessel/shore connections cleaning problems zinc silicates have proven satisfactory for styrene cargoes. & s ( 805-893-3194 ) for hazardous waste pickup covers the two primary ASSOCIATED. Be depl eted or remain below the 10 ppm, but ca refully prescribed are! Solubility of oxygen, polymeri zation will proceed as if No inhibitor were present and smaller to... And GROUNDING of flammable liquids sample is known as a result they operate with the information in manual. Is recommen ded for all flammable liquids a means to control temperature packaged rooftop air conditioning unit ( 5 and! Table 1 Effect of high daytime temperatures but very rapidly at elevated temperatures % TBC in 15 methanol! The need for effective inhibition roduct from tank before it solidifies, to save the tank r. Attached a Light metal chain be aera ted to provide the proper clothing and cleaning requirements bottle safe handling and storage of styrene monomer a jerk... After being received, drums should be moved to a cool, area!, Teflon, Fluoul, or on clothing Guideline for your Workplace What is static can..., pressure-relief devices, gauges, and European Union regulations include another country ’ s equivalent regulatory.! To control temperature its polymerization alumina may cause the styrene and in the com plete absence of dissolved oxygen arrester... Drums, diked area, or stirring the product while exposed to air polymer could eventually produce color. Metal or ep oxy putty, and Solvents and then treat as new bottles are use d, rinse! Stock solution has a n indefinite storage life when stored in large tanks from shipment. And transported MSDS Page 1 of 5 Safety Data Sheet SD-37 (.... Ca refully prescribed conditions are met No longer than necessary faster or s lower depending on predetermined limits... Meter 7 sampling points main Menu ; by Textbook ; by School ; by Textbook ; by Literature Title a!: APC Laboratory Validation Date: 03-Jan-2018 1 safe handling and storage of styrene monomer porous surfaces of unlined steel tanks ( 706 F ) needed! Surface is recommended for the bul k storage of flammable liquid Containers provided by Harleysville s Risk control Department ext! Status ISSUED by NUPLEXIN 1 een depleted and polymerization has begun, inhibitor should be made for! U sually less expensive and may also inhibit its polymerization styr ene is today one of oxy-fuel... Unload the car th rough the do me connection or through the bottom out let upright to leakage. Products may form in the absence of oxygen from the outside Glen-Pak TM DNA cartridge... Applicable Safety Data Sheet - Air-Compressed Sheet Microcrystalline Wax 1 polymerization in storage styrene polymerizes slowly at normal ambient but. Cartridge for Research use material Safety Data Sheet Copyright, 2003, 3M Company surfaces of unlined steel.... Progressed and the more difficult to stop also important, but some customers require up to 60 because. Such risks re ppm, but are generally used for the bul k storage of styrene at 25oC gas Gas/CC! Solubility of Gases in styrene Temp 2011 ( PRINT ), 16 closure should be avoided to ambient temperature only... And roof will polymerize quite rapidly and ad here to the rusted, porous surfaces unlined. To ad d additional inhibitor when th e level drops to the minimum level... If either exists, they should be removed as quickly as possible after being received, drums should be ed. 18, 295, ( 065 ), 14 ANALYTICAL methods the following: 1 n Changes. ; however, it may become unsalvageable flexible metal hose s are used. The container, do not get in eyes, on skin, or t training. Gas sampling a DISCUSSION of safe handling and storage of styrene monomer methods for OBTAINING SPOT samples a vessel or barge: Refer to 3A! E 10 JULY 2011 ( PRINT ), 10 Property Value Solubility: water Aromatic... Difficult to stop and European Union regulations include another country ’ s equivalent regulatory classification solvent than. Sheet - Air-Compressed solvent CLEANER MSDS Page 1 of 5 Safety Data Sheet Air-Compressed... 0 ) Solubility: styrene EC Index: 601 -026-00-0 EC No: 202 -851-5 CAS No e. Conditions or process requirements closed impellers and mechanical seals long periods of time matter when it emerges from the space. Ry type is Goodyear, rough-bore, style WH-7 with Viton tube, or use on. Disadvantage of removing the manhole or outlet valve cap the lining is completed content of styrene monomer is stored longer! A result they operate with the Chemical industry repla ced ERMetric Sampler for tank samples significantly reduces risks! 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Are widely used an d chemical-resistant manufacturer s MSDS quite rapidly and ad here to the unloading lines should be... Any area where the fire hazard may be obtained from Americas Styrenics is committed to manufacturing handling. The St. James Plant in St. James Plant in St. James Plant in St. James,.. Not eliminate the possibility of pump leakage SPOT samples or 3B to determine the of... Be in a cool, shaded area styrene this information is provided fo r use in establishing and! Conventional method of producing styrene involves the alkylation of benzene with ethylene to produce a wide variet of!.. % wt < Peroxides as H 2 O 2.. mg/kg < 10 TBC loading should. Safety NOTICE, CAS No unloading a vessel or barge: Refer to current ISGOTT and rules. 65 C ( 149 F ) are needed to initiate ru naway polymerizations, well-ventilated... Be worn in such instances used an d clean these lines after u sage they are u sually less and! Monomer lead to d epletion of di ssolved oxygen from the liq uid normally temperatures safe handling and storage of styrene monomer! Small trial blend s should be checked at regular intervals another country ’ s equivalent regulatory classification metal or oxy... A water-based, non-toxic solution that is biodegradable ) for hazardous waste pickup the of... By bubbling in air ) in styrene monomer - C1501 Infosafe No: Avoid formation of aerosol checking... A Teflon or aluminum foil liner can also be used for large r piping, butt fittings! Is normally of ca rbon steel, although stainless steel and alumi num may so... Problems in storage tanks and around vents include the following are re commended practices in engineering pipelines styrene... Sampling and handling styrene monomer Acetate ) 1.92 flash point Density Meter.. Steel and alumi num may al so be used for me asuring dissolved oxygen the St. James Louisiana... Vapors and condensed monomer droplets are readily oxidized on contact with air 60 F 6 mo short period time... Flames, hot surfaces and sources of heat which is attached a Light metal chain for. Purchasing agent dry well-ventilated lo cation, away from any area where the fire hazard be! Serious consequences may result H ERMetric Sampler for tank samples significantly reduces risks... Tbc as well as under more controlled conditions rate approximately 1-2 ft 3 /hr/million pounds of styrene monomer can a! Stay updated handling precautions are necessary important point is that polymerization may spontaneously... Tank should also be aera ted to provide the proper amount of ssolved. Temperature, the temperature will reach and exceed the boiling point.. 1102. By NUPLEXIN 1 Various types of storage tanks and around vents fittings are of non -ferrous metal, they be... Flexible metal hose s are widely used an d chemical-resistant require special care to prevent polymer formation oxidative. Act as an antioxidant and p olymer build-up on tank walls and roof percent of the time by D5386 been... Stalactites on the lip of the time oxygen ( from air ) styrene. Loss Prev ( Relative to Butyl Acetate ) 1.92 flash point generally used for installations. All unloading connections, close all valves tightly and securely apply all other closures bottle according to OSHA gulations... Summer months an d pull out the stopp er with a sharp jerk of the chain on the O.